Product ID:48082, DECAFLUOROTRIPHENYLPHOSPHINE 1X1ML (SUPDAT)
MSDS Date:02/05/1992
FSC:6810
NIIN:00N074585
MSDS Number: CCRXN

SUPELCO INC

SUPELCO PARK
BELLEFONTE, PA 16823-0048
US

Emergency Phone: 814-359-3441

Info Phone: 814-359-3441

Cage: 54968

SIGMA-ALDRICH INC.

14508 ST. LOUIS, MO 63103 US

Telephone: 314-771-5765/414-273-3850X5996

Cage: 54968

DECAFLUOROTRIPHENYLPHOSPHINE

CAS: 5074-71-5

Fraction By Weight: 0.2%

OSHA PEL N/K

ACGIH TLV: N/K

METHANE, DICHLORO-; (METHYLENE CHLORIDE) (SARA 313)

CAS: 75-09-2

RTECS: PA8050000

Fraction By Weight: 99-100%

OSHA PEL 500 PPM

ACGIH TLV: 50 PPM, A2

EPA Report Quantity: 1000 LBS

DOT Report Quantity: 1000 LBS

CHANGES. METHYLENE CHLORIDE HAS BEEN SHOWN

RTECS: 9999999ZZ

ONE STRAIN OF LAB MICE & BENIGN TUMORS IN LAB RATS.

RTECS: 9999999ZZ

NEGATIVE RESPONSE. METHYLENE CHLORIDE IS NOT BELIEVED

RTECS: 9999999ZZ

CH*2CL*2 IS METABOLIZED TO CO & CAN STRESS

RTECS: 9999999ZZ

METHYLENE CHLORIDE HAS BEEN SHOWN TO PRODUCE A

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 2
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:MAY BE FATAL IF INHALED. HARMFUL IF
SWALLOWED. CNTNS MATL(S) KNOWN TO CA TO CAUSE CANCER. LACHRIMATION,
IRRITATES SKIN, DERM, HDCH, DIZZ, NARCOSIS, LIVER & KIDNEY DMG.
CHLOROCARB MATLS HAVE PRDCED SEN SIT OF MYOCARDIUM TO EPINEPHRINE
IN LABANIMALS & COULD HAVE SIMILAR EFT IN HUMANS. ADRENOMIMETICS
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:METHYLENE CHLORIDE:IARC MONOGRAPHS,
SUPP, VOL 7, PG 194, 1987:GROUP 2B. NTP 7TH ANNUAL RPT ON CARCINS,
1994:(SUPP DATA)
Effects of Overexposure:HLTH HAZS:(E.G. EPINEPHRINE) MAY BE
CONTRAINDICATED EXCEPT FOR LIFE-SUSTAINING USES IN HUMANS
ACUTELY/CHRONICALLY EXPOSED TO CHLOROCARBS . SEVERAL CHRONIC INHAL
STUDIES REPORTED BY NIOSH REVEALE D THAT TEST ANIMALS EXPOSED TO
METHYLENE CHLORIDE CONCS AS HIGH AS 10,000 PPM SHOWED SLIGHT LIVER
& KIDNEY (ING 3)
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES:FLUSH W/WATER FOR @ LST 15 MIN. SKIN:PROMPTLY WASH
W/MILD SOAP & LG VOLS OF WATER. REMOVE CONTAM CLTHG. INHAL:IMMED
MOVE TO FRESH AIR. GIVE OXYG IF BRTHG IS LABORED. IF BRTHG STOPS,
GIVE ARTF RES P. CONT MD. NEVER ADMIN ADRENALIN FOLLOWING CH2C12
EXPOS. INCR SENSIT OF HEART TO ADRENALIN MAY BE CAUSED BY OVEREXP
TO CH2C12. INGEST:NEVER GIVE ANYTHING BY MOUTH TO AN UNCON PERSON.
NEVER (SUPDAT)

Lower Limits:12.0%
Upper Limits:19.0%
Extinguishing Media:WATER, CO*2, DRY CHEMICAL.
Fire Fighting Procedures:WEAR NIOSH APPROVED PRESSURE DEMAND SCBA &
FULL PROTECTIVE EQUIPMENT .
Unusual Fire/Explosion Hazard:THE FOLLOWING TOXIC VAPORS ARE FORMED
WHEN THIS MATERIAL IS HEATED TO DECOMPOSITION:HYDROGEN CHLORIDE,
PHOSGENE, OXIDES OF PHOSPHORUS.

Spill Release Procedures:TAKE UP WITH ABSORBENT MATERIAL. VENTILATE
AREA. METHYLENE CHLORIDE VAPORS ARE HEAVIER THAN AIR AND WILL
COLLECT IN LOW AREAS.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:REFRIGERATE IN SEALED CONTAINER.
Other Precautions:POSSIBLE CANCER HAZARD. NO SMOKING IN AREA OF USE. DO
NOT USE IN THE GENERAL VICINITY OF ARC WELDING, OPEN FLAMES OR HOT
SURFACES. HEAT AND/OR UV RADIATION MAY CAUSE THE FORMATION OF HCL
AND/OR PHOSGE NE .

Respiratory Protection:WEAR NIOSH APPROVED FACE MASK WITH ORGANIC VAPOR
CANNISTER. WEAR NIOSH APPROVED RESPIRATORY PROTECTION.
Ventilation:USE ONLY IN WELL VENTILATED AREA.
Protective Gloves:WEAR NEOPRENE GLOVES.
Eye Protection:ANSI APPROVED CHEM WORKERS GOGGS .
Other Protective Equipment:ANSI APPROVED EMERGENCY EYE WASH AND DELUGE
SHOWER .
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
MFR TRADE/PART #:CH2CL2 2000 UG/ML. CNDTNS (STAB):HOT GLOWING
SURFS/ELEC ARCS CAN DECOMP TO FORM HYDROGEN CHLORIDE GAS & TRACES
OF PHOSGENE. EXPLAN OF CARCIN:ANTIC TO BE CARCIN. ANIMAL:LUNG,
LIVER, SA LIVARY, MAMMARY GLAND (TUMORS). FIRST AID PROC:TRY TO
MAKE AN UNCON PERSON VOMIT. DO NOT INDUCE VOMIT. IMMED CONT MD.

Boiling Pt:B.P. Text:104F,40C
Melt/Freeze Pt:M.P/F.P Text:207F,97C
Vapor Pres:349 @ 20C
Vapor Density:2.93 @ 20C
Spec Gravity:1.320 G/ML
Evaporation Rate & Reference:0.71 (ETHER=1)
Solubility in Water:1.6
Appearance and Odor:COLORLESS LIQUID; ETHER-LIKE ODOR.
Percent Volatiles by Volume:100

Stability Indicator/Materials to Avoid:YES
STRONG BASES, OXIDIZING AGENTS.
Stability Condition to Avoid:NOT APPLICABLE.
Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, OXIDES OF
PHOSPHORUS.
Conditions to Avoid Polymerization:LIQ OXYGEN/OTHER STRONG OXIDANTS MAY
FORM EXPLO MIX W/METHYLENE CHLORIDE. MATL/ITS VAPS WHEN IN CONT
W/FLAMES, (SUPDAT)

Waste Disposal Methods:COMPLY WITH ALL APPLICABLE FEDERAL, STATE OR
LOCAL REGULATIONS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.